锑
硒化物
太阳能电池
材料科学
带隙
正交晶系
薄膜
化学浴沉积
开路电压
短路
分析化学(期刊)
化学工程
化学
纳米技术
光电子学
硒
结晶学
晶体结构
冶金
有机化学
物理
量子力学
电压
工程类
作者
Fabiola De Bray Sánchez,M. T. S. Nair,P. K. Nair
标识
DOI:10.1016/j.apsusc.2018.05.076
摘要
Antimony sulfide (Sb2S3) with an optical bandgap (Eg) of 1.88 eV and antimony selenide (Sb2Se3) with Eg 1.1 eV, both of orthorhombic crystalline structure, offer a unique opportunity to prepare solar cell absorbers of Eg, 1.3–1.6 eV poised toward economically viable, non-toxic and 'earth-abundant" devices. We prepared chemical precipitates of Sb-S-Se from solutions containing potassium antimony tartrate, thioacetamide and selenosulfate, which were used as sources in vacuum thermal evaporation to produce thin films (280–300 nm) of composition, Sb2SxSe3−x (x = 0.7–2). The Eg of 1.43–1.6 eV and photoconductivity, 4 × 10−5 and 8 × 10−7 Ω−1 cm−1, respectively of these films help to combine a high open circuit voltage (Voc) of 0.609 V with a conversion efficiency (η) 5.5% or a Voc of 0.503 V with η of 6.2%. A dual-crucible thermal evaporation system allowed the preparation of absorber films of varying composition (x) in the cell structure, SnO2:F (FTO)/CdS/Sb2SxSe3−x/C-Ag. The cell area were, 0.2–0.8 cm2. A prototype module of seven series-connected cells of area 1 cm2 each produced a Voc of 3.5 V, short circuit current 12 mA at η, 2.4%. Evaluation of the composition of the Sb2SxSe3−x films through gracing incidence X-ray diffraction is illustrated; and device parameters and solar cell perspectives of these materials are presented.
科研通智能强力驱动
Strongly Powered by AbleSci AI