Battery-like flexible supercapacitors from vertical 3D diamond/graphite composite films on carbon cloth

超级电容器 假电容器 材料科学 电容 石墨 钻石 复合数 电池(电) 碳纤维 电极 纳米技术 储能 电解质 电容器 复合材料 化学工程 光电子学 电气工程 功率(物理) 化学 电压 物理 物理化学 量子力学 工程类
作者
Junjie Long,Lei Guan,Jian Wang,Huiqiang Liu,Bing Wang,Ying Xiong
出处
期刊:Carbon [Elsevier]
卷期号:197: 400-407 被引量:7
标识
DOI:10.1016/j.carbon.2022.06.042
摘要

Flexible supercapacitors (SCs) based on carbon nanomaterials are one of the promising energy storage devices for wearable electron devices. However, their low energy density and cycle stability severely restrict further practical applications. The development of unique capacitor electrodes is expected largely to overcome these challenges. Herein, vertical 3D diamond/graphite (DG) composite films are directly grown on carbon cloth (CC) using a microwave plasma chemical vapor deposition (MPCVD) technique. Thin, straight nanosheets, consisted of diamond as core and graphite as shell, are interlaced with each other to form a 3D porous structure. As a binder- and additive-free electrode material, the DG/CC electrodes are used to construct electrical double layer capacitors (EDLCs) in diluted H2SO4 solution and pseudocapacitors (PCs) using Fe(CN)63−/4- redox electrolytes. Both EDLCs and PCs exhibit large specific capacitance and high capacitance retention. When assembled as all-solid-state flexible symmetric SCs, they offer high full-cell capacitances of 30.4 and 143.6 mF cm−2 at 10 mV s−1 for EDLCs and PCs, respectively. The power densities are 6.3 μW cm−2 and 3.0 mW cm−2 for EDLCs and PCs, together with their energy densities of 3.7 and 86.2 μWh cm−2, respectively. As flexible SCs, the specific capacitance can be completely recovered for EDLCs and has only about 6.7% loss for PCs even after the U-shape bending state. Such vertical 3D porous DG films are thus promising for the construction of high-performance battery-like SCs for an intelligent wearable energy supplier.
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