化学
选择性
催化作用
纳米颗粒
二烯
色散(光学)
配体(生物化学)
组合化学
化学工程
有机化学
生物化学
天然橡胶
物理
受体
光学
工程类
作者
Xiaoqian Jia,Shihua Wang,Yu Fan
标识
DOI:10.1016/j.jcat.2015.04.017
摘要
We proposed a novel strategy for producing highly dispersed Pd particles on ZIF-8 via the anchoring effect of the carboxyl groups incorporated into the ligand of ZIF-8. The as-synthesized Pd nanoparticles supported on the in situ carboxyl-functionalized ZIF-8 showed excellent activity and selectivity for diene hydrogenation due to the high dispersion of Pd nanoparticles and the interaction between the Pd nanoparticles and carboxyl groups. This method opens a new and simple route for greatly improving the dispersion of supported Pd nanoparticles.
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