Catalytic performance and mechanism of bismuth molybdate nanosheets decorated with platinum nanoparticles for formaldehyde decomposition at room temperature

Catalytic oxidation at room temperature is considered as a promising strategy for removal of formaldehyde (HCHO), a widely occurring indoor air pollutant. A series of Bi2MoO6 nanosheets were prepared via one-step hydrothermal synthesis in this study, followed by decoration with Pt nanoparticles (NPs). The catalyst with Bi2MoO6 support prepared at 180 °C exhibited high and stable activity in catalytic oxidation of HCHO at room temperature. The excellent catalytic performance was attributed to its large specific area and pore volume, high level of surface active oxygen species, high content of metallic Pt NPs, and abundant oxygen vacancies. The good synergy and interaction between Pt and Bi2MoO6 promoted electron transfer, and facilitated the adsorption and oxidation of HCHO. The electronic interaction between Pt NPs and Bi2MoO6 accelerated the activation of oxygen species due to weakening of the surface BiO or MoO bonds adjacent to Pt NPs. Infrared spectra indicated that dioxymethylene and formate species were the main intermediates of HCHO oxidation. Density functional theory calculations showed that the dehydrogenation of HCO2, with an energy barrier of 282.1 kJ/mol, was the rate-determining step in catalytic oxidation process. This study provides new insights on the construction of high-efficiency catalysts for indoor formaldehyde removal.