纳米孔
金属有机骨架
分离(统计)
化学工程
材料科学
纳米技术
多孔性
金属
吸附
纳米孔
多孔介质
介孔材料
化学
计算机科学
有机化学
冶金
机器学习
作者
Yusheng Zhao,Amr I. Abdel-Fattah,Hongwu Xu,Donald D. Hickmott
出处
期刊:CrystEngComm
[The Royal Society of Chemistry]
日期:2010-04-26
卷期号:12 (5): 1337-1353
被引量:145
摘要
This Highlight explores the progress and perspective in studies of metal–organic frameworks (MOFs), a new class of nanoporous materials, particularly suited for storage and separation applications related to energy utilization and environmental remediation. Since the discovery of the first MOF compound, hundreds of different MOFs have been developed and reported. MOFs are generally synthesized by self-assembly of metal ions/clusters as coordination centers and organic ligands as linkers. They possess intriguing chemical and physical properties and are structurally tunable, thermally stable and mechanically sound. MOFs are increasingly proving to be a superior class of materials for state-of-the-art applications in crystal engineering, chemistry, and materials science. In this Highlight, we present general routes for MOFs synthesis, discuss reticular design of their pore structures, and show some of their remarkable applications, especially in the areas of storage and separation.
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