Designing the heterostructured FeWO4/FeS2 nanocomposites for an enhanced photocatalytic organic dye degradation

The present study, reports a facile approach for the synthesis of FeWO4/FeS2 nanocomposites were demonstrated through hydrothermal method. The surface morphology, crystalline structure, chemical composition, optical properties of the prepared samples was analysed by different various technique. The result observed analysis indicates that, the formation of heterojunction by 2:1wt% of FeWO4/FeS2 nanohybrid has the lowest recombination rate of electron-hole pairs and the least electron transfer resistance. Due to its the broad absorption spectral range and preferable energy band gap, the (2:1) FeWO4/FeS2 nanohybrid photocatalyst exhibits an excellent ability to remove MB dye when exposed to UV–Vis. Light irradiation. Its photocatalytic activity of (2:1) FeWO4/FeS2 nanohybrid is higher than other as prepared samples due to its synergistic effects, enhanced light absorption and high charge carrier separation. Radical trapping experimental result implies that the photo-generated free electrons and hydroxyl radials are essential to degrade the MB dye. Furthermore, a possible future mechanism for FeWO4/FeS2 nanocomposites photocatalytic activity was discussed. Moreover, the recyclability analysis demonstrated that the FeWO4/FeS2 nanocomposites can be recycled multiple times. The enhanced photocatalytic activity of 2:1 FeWO4/FeS2 nanocomposites is promising for the further application of visible light driven photocatalyst in wastewater treatment.