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양성자 조사가 316 스테인리스강의 미세조직과 표면산화 특성에 미치는 영향

辐照 材料科学 应力腐蚀开裂 晶界 质子 奥氏体不锈钢 冶金 奥氏体 腐蚀 放射化学 微观结构 辐射损伤 化学 核物理学 物理
作者
임연수,김동진,황성식,최민재,조성환
出处
期刊:Corrosion science and technology [The Corrosion Science Society of Korea]
卷期号:20 (3): 158-168
标识
DOI:10.14773/cst.2021.20.3.158
摘要

Austenitic 316 stainless steel was irradiated with protons accelerated by an energy of 2 MeV at 360 ℃, the various defects induced by this proton irradiation were characterized with microscopic equipment. In our observations irradiation defects such as dislocations and micro-voids were clearly revealed. The typical irradiation defects observed differed according to depth, indicating the evolution of irradiation defects follows the characteristics of radiation damage profiles that depend on depth. Surface oxidation tests were conducted under the simulated primary water conditions of a pressurized water reactor (PWR) to understand the role irradiation defects play in surface oxidation behavior and also to investigate the resultant irradiation assisted stress corrosion cracking (IASCC) susceptibility that occurs after exposure to PWR primary water. We found that Cr and Fe became depleted while Ni was enriched at the grain boundary beneath the surface oxidation layer both in the non-irradiated and proton-irradiated specimens. However, the degree of Cr/Fe depletion and Ni enrichment was much higher in the proton-irradiated sample than in the non-irradiated one owing to radiation-induced segregation and the irradiation defects. The microstructural and microchemical changes induced by proton irradiation all appear to significantly increase the susceptibility of austenitic 316 stainless steel to IASCC.

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