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The hydrogenation of carbon dioxide into formic acid (FA) with Earth-abundant metals is a vibrant research area because FA is an attractive molecule for hydrogen storage. We report a cyclopentadienyl iron tricarbonyl complex that provides up to 3000 turnover number for carbon dioxide hydrogenation when combined with a catalytic amount of the chromium dicarboxylate MOF MIL-53(Cr). To date, this is the highest turnover number reported in the presence of a phosphine-free iron complex
用地球上丰富的金属将二氧化碳氢化成甲酸(FA)是一个充满活力的研究领域,因为FA是一种有吸引力的储氢分子。我们报道了一种环戊二烯基三羰基铁络合物,当与催化量的二羧酸铬MOF MIL-53(Cr)结合时,该络合物为二氧化碳氢化提供高达3000周转数。迄今为止,这是在无膦铁络合物存在下报告的最高周转数
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