材料科学
储能
热传导
铅(地质)
陶瓷
调制(音乐)
领域(数学分析)
工程物理
纳米技术
复合材料
热力学
工程类
声学
数学分析
功率(物理)
物理
数学
地貌学
地质学
作者
Jiawei Wu,Tiantian Zhang,H. S. Zhao,Pei Han,Ninghui Sun,Junyi Du,Liwen Zhang,Ye Zhao,Yong Li,Xihong Hao
标识
DOI:10.1016/j.ceramint.2024.01.376
摘要
The main factors that limit the practical application of bismuth ferrite-based energy storage ceramics are their low breakdown electric field strength and large remnant polarization. Here, we achieve high energy storage behavior in (0.72-x)BiFeO3-0.28BaTiO3-xLa(Mg1/2Zr1/2)O3 (BF-BT-xLMZ) ferroelectric ceramics through directional defect modulation based on a transformation of the conductance mechanisms. The systematic experimental analysis coupled with the vacancy sink model suggests that the introduction of LMZ changes the trap-filled-limit conduction mode dominated by oxygen vacancy, leading to 4 times enhancement of the breakdown electric field in BF-BT-0.2LMZ. Meanwhile, the induced nanodomains create a size effect that effectively reduces the remnant polarization, resulting in an increase in efficiency by 3.5 times. As a result, the recoverable energy storage density of the ceramic reaches an outstanding 4.2 J/cm3, together with a high efficiency of 75.2 %. This work provides a feasible strategy for the development of ferroelectric family in the field of high-energy storage.
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