阳极
储能
分离器(采油)
阴极
纳米技术
材料科学
有机自由基电池
能量密度
多孔性
电极
电解质
工程物理
化学
电气工程
复合材料
工程类
物理
物理化学
功率(物理)
热力学
量子力学
作者
Zhuo Wang,Fei Pan,Qi Zhao,Menglan Lv,Bin Zhang
标识
DOI:10.3389/fchem.2022.1055649
摘要
Recently, how to enhance the energy density of rechargeable batteries dramatically is becoming a driving force in the field of energy storage research. Among the current energy storage technologies, the lithium-sulfur (Li-S) batteries are one of the most promising candidates for achieving high-capacity and commercial batteries. The theoretical energy density of Li-S batteries reaches to 2,600 Wh kg-1 with the theoretical capacity of 1,675 mA h g-1. Therefore, Li-S batteries are considered as the great potential for developing future energy storage technology. However, some of problems such as Li dendrites growth, the shuttle effect of sulfides and the electronic insulation feature of sulfur, have brought obstacles to the development of Li-S batteries. The covalent organic frameworks (COFs) are a series of porous materials with different topological structures, which show the versatile characteristics of high specific surface area, permanent pores, ordered porous channels and tunable internal structure. Potentially, their ordered channels and extended conjugated frameworks could facilitate rapid Li-ion diffusion and electron transport for the remarkable rate capability. On the basis of these merits, the COFs become the potential electrode materials to solve the above serious problems of Li-S batteries. In this mini review, we summarize the research progress of COFs utilized as electrode materials in the Li-S batteries, including the cathode, separator and anode materials. Accordingly, the outlook of COFs as electrodes for future development in Li-S batteries is also given.
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