阳极
硫化
材料科学
纳米颗粒
电化学
化学工程
碳化
金属有机骨架
氮气
碳纤维
金属
过渡金属
纳米技术
电极
化学
复合材料
冶金
硫黄
催化作用
有机化学
吸附
扫描电子显微镜
物理化学
工程类
复合数
作者
Xiaoqin Liu,Xiaoyan Li,Xiaoli Lü,Xiao‐Ting He,Na Jiang,Yujing Huo,Xu Cheng,Dunmin Lin
标识
DOI:10.1016/j.jallcom.2020.157132
摘要
Transition metal sulfides (TMSs) have been considered as the most promising candidates for anode materials of sodium-ion batteries (SIBs) due to their high theoretical specific capacity. However, large volume expansion caused by conversion reaction during sodiation-desodiation processes generally leads to poor structural stability. Herein, metal-organic framework (MOF)-derived in-situ nitrogen-doped partially graphitized carbon-encapsulated CuS nanoparticles ([email protected]) has been successfully prepared via a two-step process of carbonization and sulfidation. The preparation strategy using Cu-MOF as precursor realizes in-situ encapsulation of CuS into nitrogen-doped carbon matrix, simultaneously endowing the [email protected] with high conductivity and rigid structure protection. As a result, the [email protected] shows an excellent electrochemical properties as an anode of SIBs: delivering the satisfying rate capability of 259.4 mAh g−1 at 5 A g−1 and exhibiting the high reversible capacity of 300.2 mAh g−1 after 1200 cycles at 5 A g−1 with an ultra-low capacity decay of 0.0035% per cycle. This study proposes an effective strategy to develop novel anodes with excellent cycling and rate properties for SIBs by encapsulating active nanoparticles into carbon matrix.
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