非阻塞I/O
材料科学
钝化
钙钛矿(结构)
分子
兴奋剂
离子
能量转换效率
纳米技术
化学工程
光电子学
催化作用
图层(电子)
有机化学
化学
工程类
作者
Nan Yan,Yang Cao,Zhiwen Jin,Yucheng Liu,Shengzhong Liu,Zhimin Fang,Jiangshan Feng
标识
DOI:10.1002/adma.202403682
摘要
Abstract Functional agents have been verified to efficiently enhance device performance of perovskite solar cells (PSCs) through surface engineering. However, the influence of intrinsic characteristics of molecules on final device performance has been overlooked. Here, we develop a surface reconstruction strategy to enhance the efficiency of inverted PSCs by mitigating the adverse effects of lead chelation (LC) molecules. We choose bathocuproine (BCP), as the representative of LC molecules for its easy accessibility and outstanding optoelectronic properties. During this strategy, BCP molecules on perovskite surface are first dissolved in solvents and then captured specially by undercoordinated Pb 2+ ions, preventing adverse n‐type doping by the molecules themselves. In this case, the BCP molecule exhibits outstanding passivation effect on perovskite surface, which leads to an obviously increased open‐circuit voltage ( V OC ). Therefore, a record PCE of 25.64% for NiO x ‐based inverted PSCs is achieved, maintaining over 80% of initial efficiency after exposure to ambient condition for ∼1500 hours. This article is protected by copyright. All rights reserved
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