Geochemical Evidence of Plume Sources for High-MgO Lavas in the Western Kunlun Orogenic Belt

Abstract Plume-derived high-MgO lavas provide important information on the lithological, thermal and chemical variations of Earth’s deep mantle. Here we present results from detailed field, mineralogical and geochemical studies of Late Permian–Late Triassic high-MgO lavas near the Chalukou area in the Western Kunlun (WK) orogenic belt, NW China. The major element compositions of the lavas show extremely high MgO contents (26.6–33.8 wt %) in accordance with olivine accumulation. The parental magma is inferred to be picritic in composition with MgO of 17.2 ± 0.9 wt %. Olivine Zn/Fe and Mn/Zn ratios suggest a peridotite-dominated source with a minor fraction of pyroxenite. The temperature and oxygen fugacity estimates based on multi-methods including olivine-melt Mg–Fe equilibria, Al-in-olivine and olivine–spinel thermometry and oxybarometer yield a mantle potential temperature of 1522–1556 °C and high oxygen fugacity of FMQ (fayalite-magnetite-quartz) + 0.93. The H2O contents in the picrite flows are estimated as 3.67 ± 1.0 wt %, indicating the volatile-rich nature of parental magma and its mantle source. The immobile trace element features show that the WK picrites are OIB (oceanic island basalt)-like, with the enrichment in light rare earth elements and positive Nb, Ta, Zr and Hf anomalies. Furthermore, the Nd–O–Os isotopes display typical mantle values without involvement of recycled materials. Our results suggest the high-MgO volcanism in the WK orogenic belt originated from a volatile-rich plume source.