多硫化物
材料科学
锡
阳极
氮化钛
化学工程
电解质
电极
纳米线
氮化物
储能
分离器(采油)
兴奋剂
纳米技术
氧化锡
电化学
化学
冶金
光电子学
图层(电子)
功率(物理)
物理化学
工程类
物理
热力学
量子力学
作者
Yoongon Kim,Yuseong Noh,Joongmyeon Bae,Hyo‐Jun Ahn,Minho Kim
标识
DOI:10.1016/j.jechem.2020.08.050
摘要
Lithium-sulfur (Li–S) batteries have attracted considerable attention as next-generation energy storage devices owing to their high theoretical specific capacity and safety. However, the commercialization of Li–S batteries is hindered by critical issues, including the migration of the dissolved lithium polysulfides (LiPSs) from the sulfur electrode to the lithium metal anode, resulting in poor cycling stability. Here, we report a multifunctional interlayer configured with an N-doped carbon framework and titanium nitride nanowires on a polypropylene separator (NC/TiN [email protected]) to suppress the polysulfide shuttling problem. NC/TiN [email protected] can be obtained by electrospinning and the subsequent scalable solution-based vacuum filtration. The one-dimensional structure of the TiN NWs can shorten the Li-ion diffusion distance with large electrode/electrolyte interfaces. Furthermore, the N-doped carbon framework in the NWs enables facile electron transportation and allows the suppression of the shuttle effect to improve the electrochemical reaction kinetics. The Li–S battery with a NC/TiN [email protected] separator exhibited enhanced cycling stability and rate capability, indicating that this could be a new research direction for Li–S batteries.
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