桤木
Diels-Alder反应
路易斯酸
化学
催化作用
有机化学
生物
生态学
作者
Pascal Vermeeren,Trevor A. Hamlin,Israel Fernández,F. Matthias Bickelhaupt
标识
DOI：10.1002/anie.201914582
摘要
The Lewis acid(LA)-catalyzed Diels-Alder reaction between isoprene and methyl acrylate was investigated quantum chemically using a combined density functional theory and coupled-cluster theory approach. Computed activation energies systematically decrease as the strength of the LA increases along the series I
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