铑
环加成
化学
级联
原子经济
盐变质反应
复分解
组合化学
有机合成
立体化学
催化作用
有机化学
聚合物
色谱法
聚合
作者
Deepak R. Mishra,Bhabani Shankar Panda,Smita Nayak,Jasmine Panda,Seetaram Mohapatra
标识
DOI:10.1002/slct.202200531
摘要
Abstract Five membered N ‐heterocycles are significant targets in organic synthesis because of their ubiquitous existence in bioactive natural products and pharmaceuticals. Over the past decade a compelling attractiveness has grown to develop rhodium complex catalysed efficient and atom‐economic chemistry to access structurally diverse N ‐heterocyclic frameworks. This present review enlightens notable progresses and advances in synthesis of 5‐membered N ‐heterocycles via rhodium catalysed cascade reactions (annulations, C−H/C−C activation, cycloaddition, rearrangement, cyclization, metathesis) from 2018–2021.
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