微型多孔材料
亚硝酸盐
对苯二酚
儿茶酚
热解
材料科学
检出限
电化学
电极
电化学气体传感器
无机化学
核化学
化学
色谱法
有机化学
硝酸盐
物理化学
作者
Zhenyong Lu,Yue Wang,Yaming Zhu,Yasushi Hasebe,Zhiqiang Zhang
标识
DOI:10.1002/slct.202200148
摘要
In this study, popcorn-derived microporous carbon (PPC) was prepared by pyrolysis method under KOH activation, which was used as an electrochemical sensor material for simultaneous detection of hydroquinone (HQ), catechol (CC), and nitrite (NT). The prepared PPC/GCE exhibited highly electrocatalytic activity to the oxidation of HQ, CC and nitrite. The oxidation peaks for HQ (111 mV), CC (216 mV), and NT (854 mV) were well separated under the optimized conditions. The PPC/GCE showed a wide linear range of 3.0–700 μM, 3.0–500 μM and 5.0–10000 μM for HQ, CC and NT with detection limits of 1.45 μM, 0.49 μM and 1.5 μM, respectively. The KOH-activated PPC is a promising electrode material for fabricating selective and sensitive electrochemical sensors.
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