纳米复合材料
材料科学
反射损耗
纳米颗粒
微观结构
复合材料
碳化
静电纺丝
吸收(声学)
复合数
化学工程
纳米技术
聚合物
扫描电子显微镜
工程类
作者
Yue Liu,Zhihui Zeng,Sinan Zheng,Jing Qiao,Wei Liu,Lili Wu,Jiurong Liu
标识
DOI:10.1016/j.compositesb.2022.109800
摘要
A type of nickel/manganese oxide (Ni/MnO)/carbon nanocomposite fibers were prepared via a facile and scalable electrospinning and carbonization approach. In comparison to the pure carbon showing a severe agglomeration, the uniformly embedded MnO and Ni nanoparticles promoted the formation of the fibrous carbon-based nanocomposites with an average diameter of 250 nm and a rough surface. The synergistic coactions of the MnO nanoparticles acting as impedance modulating mediator, the magnetic Ni nanoparticles, and the conductive, fibrous carbon with large aspect ratio and rough surface contributed to the excellent electromagnetic wave (EMW) absorbing performance of the nanocomposites. The nanocomposites with a MnO/Ni ratio of 1:1 exhibited an effective absorption bandwidth of 6.5 GHz at a thickness of 2.9 mm and a minimum reflection loss of −53.23 dB at a thickness of 2.3 mm. The EMW absorption mechanisms of the nanocomposite fibers were discussed at length, which showed the importance of the multi-component building units and microstructure for achieving high EMW absorbing performance. This work thus suggested a convenient, facile, and scalable manufacturing approach for constructing high-performance multi-component nanocomposite fiber based EMW absorbing materials.
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