普鲁士蓝
材料科学
碳纤维
化学工程
催化作用
分解水
热解
析氧
电化学
纳米技术
化学
物理化学
复合数
电极
复合材料
有机化学
光催化
工程类
作者
Zhijuan Li,Xiaodong Wu,Xian Jiang,Bin-Bin Shen,Zixuan Teng,Dongmei Sun,Gengtao Fu,Yawen Tang
出处
期刊:Advanced powder materials
[Elsevier]
日期:2022-04-01
卷期号:1 (2): 100020-100020
被引量:127
标识
DOI:10.1016/j.apmate.2021.11.007
摘要
Developing high-efficiency and low-cost catalysts towards oxygen evolution reaction (OER) is extremely important for overall water splitting and rechargeable metal−air batteries. Herein we propose a promising organometallic coordination polymer (OCP) induced strategy to construct hierarchical N-doped carbon framework with NiFe nanoparticles encapsulated inside (Nx[email protected]–C) as a highly active and stable OER catalyst. The synthesis of OCP precursor depends on the unique molecular structure of iminodiacetonitrile (IDAN), which can coordinate with metal ions to form Ni2Fe(CN)6 with prussian blue analogs (PBA) structure. Unlike previous PBA-induced methods, the thickness of the carbon layer covering the surface of the metal core can be well controlled during the pyrolysis through adjusting the amount of IDAN, which builds a wonderful bridge for investigating the relationship between carbon layer thickness and catalytic performance. Both the experimental characterizations and theoretical studies validate that a suitable carbon layers thickness leads to optimal OER activity and stability. By optimizing the structure and composition, the optimized Ni3[email protected]–C with hierarchical framework exhibits the low overpotentials (260 mV at 10 mA cm−2; 320 mV at 50 mA cm−2), improved kinetics (79 mV dec−1), and robust long-term stability, which exceeds those of benchmark RuO2.
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