嬉戏
开环复分解聚合
烯烃复分解
复分解
聚合
高分子科学
纳米技术
聚合物
材料科学
高分子
化学
复合材料
生物化学
作者
Christopher W. Bielawski,Robert H. Grubbs
标识
DOI:10.1016/j.progpolymsci.2006.08.006
摘要
Since the discovery of olefin metathesis in the mid-1950s, there has been great interest in using this versatile reaction to synthesize macromolecular materials. More recently, living ring-opening metathesis polymerization (ROMP), a variation of the olefin metathesis reaction, has emerged as a particularly powerful method for synthesizing polymers with tunable sizes, shapes, and functions. The technique has found tremendous utility in preparing materials with interesting biological, electronic, and mechanical properties. This review covers the fundamental aspects of living ROMP and briefly traces its historical development from a catalyst-design perspective. Highlights from the recent literature are used to illustrate the utility of living ROMP in the preparation of macromolecular materials with advanced structures and functions. A discussion on the current status of state-of-the-art catalysts for use in living ROMP reactions as well as opportunities for the future concludes this review.
科研通智能强力驱动
Strongly Powered by AbleSci AI