化学
烷基化
试剂
电泳剂
水解
有机化学
药物化学
组合化学
催化作用
作者
Hiroshi Goda,Makoto Sato,Hirotaka Ihara,Chuichi Hirayama
出处
期刊:Synthesis
[Georg Thieme Verlag KG]
日期:1992-01-01
卷期号:1992 (09): 849-851
被引量:18
摘要
5-Substituted 2-(α-alkoxyimino)ethylthiophenes 4-8 are obtained by the reaction of 2-(α-alkoxyimino)ethylthiophenes 3 and electrophilic reagents. Hydrolysis of thiophenes 4-8 produces 5-substituted 2-acetylthiophenes 9-13, respectively. Compounds 3 are easily obtained either by the reaction of 2-acetylthiophene (1) and an O-alkylhydroxylamine or by oxidation of 1 followed by O-alkylation.
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