试剂
化学
苯胺
组合化学
基质(水族馆)
配体(生物化学)
有机化学
受体
生物化学
海洋学
地质学
作者
Shiqi Chen,Si Cao,Chaoyang Liu,Qingji Wang,Xiaorui Ren,Hang Huang,Zhihong Peng,Xi Wang
出处
期刊:Organic Letters
[American Chemical Society]
日期:2021-09-22
卷期号:23 (19): 7428-7433
被引量:18
标识
DOI:10.1021/acs.orglett.1c02636
摘要
A transition metal/ligand-free disulfuration of anilines with disulfur transfer reagents (dithiosulfonate or tetrasulfide) is reported herein. The reaction, which can be considered as a reductive disulfuration variation of the classic Sandmeyer reaction, is performed under mild conditions and exhibits broad scope across the aniline substrate and disulfur transfer reagent classes. The gram-scale synthesis of disulfides is successfully achieved through this method, rendering the approach highly valuable.
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