激子
卤化物
量子产额
光致发光
铜
金属卤化物
发光
激发态
化学物理
材料科学
晶体工程
溴化物
金属
光化学
纳米技术
晶体结构
光电子学
结晶学
化学
凝聚态物理
物理
无机化学
超分子化学
荧光
光学
原子物理学
冶金
作者
Hui Peng,Yan Tian,Zhenheng Zhang,Xinxin Wang,Tao Huang,Ting Dong,Yonghao Xiao,Jianping Wang,B. S. Zou
标识
DOI:10.1021/acs.jpcc.1c05065
摘要
Recently, Cu(I)-based metal halides have gained great attention due to their fascinating structures and optoelectronic properties. Here, we report the synthesis, crystal structure, and photophysical properties of zero-dimensional (0D) organic copper bromide hybrid, where the isolated [CuBr2]− units are encircled by the organic cation of TBA+ (TBA+ = tetrabutylammonium cation), forming the bulk assembly of periodic 0D blocks. Moreover, this 0D structure enables strong electron–phonon interaction to promote the formation of a self-trapped excited state that shows a bright broadband cyan emission with a photoluminescence quantum yield (PLQY) of 55% for (TBA)CuBr2 single crystals (SCs). Particularly, the as-synthesized compound shows extraordinary antiwater stability, and its PL intensity remains above 99.1% after soaking in water for 24 h. This work illustrates that the water-sensitive Cu(I) can also be used as a high antiwater stability luminescent material by introducing appropriate multifunctional organic ligands, thus opening up a new route for high antiwater materials based on lead-free metal halides.
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