化学
检出限
双酚A
内分泌干扰物
电化学
电极
循环伏安法
碳纤维
色谱法
有机化学
内分泌系统
材料科学
物理化学
复合材料
环氧树脂
复合数
激素
生物化学
作者
Min‐Soo Kim,Young Eun Song,Jiu-Qiang Xiong,Kyoung‐Yeol Kim,Min Jang,Byong‐Hun Jeon,Jung Rae Kim
标识
DOI:10.1016/j.jelechem.2020.114907
摘要
2,2-Bis (4-hydroxyphenyl) propane (bisphenol A) is a precursor in many industrial and manufactural resins, plastics, and polycarbonate, as well as an endocrine disruptor in humans and animals. Therefore, the real-time sensing and in-situ removal of BPA are in strong demand. This study evaluated a method for the electrochemical detection of BPA using a carbon felt electrode. BPA was detected by cyclic voltammetry. During detection, the BPA was electropolymerized to a non-conductive lump and layer on the electrode surface. Simultaneously, the capacitance and electrochemical properties of the carbon felt decreased. The peak current and BPA concentration showed a linear correlation; the estimated detection limit was 4.78 × 10−7 M. The BPA-electropolymerized carbon felt could be regenerated successfully by ultrasonication. The detection and quantification of BPA in real water samples showed satisfactory recoveries of 98.4–101.0%. The carbon felt-based electrochemical analysis exhibited high sensitivity and reusability, making it applicable to the in-situ and on-site detection and removal of endocrine disruptors, such as BPA.
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