物理吸附
吸附
氮气
三聚氰胺
六亚甲基四胺
拉曼光谱
化学
X射线光电子能谱
兴奋剂
巴(单位)
核化学
分析化学(期刊)
材料科学
有机化学
化学工程
光学
物理
工程类
气象学
光电子学
作者
Lucas Spessato,Vitor Anthony Duarte,Jhessica M. Fonseca,Pedro Augusto Arroyo,Vitor C. Almeida
标识
DOI:10.1016/j.jcou.2022.102013
摘要
Nitrogen-doped activated carbons (NACs) were produced from Brazil nut shells (BNS) using a concurrent procedure of KOH-activation and N-doping using melamine (MM), hexamethylenetetramine (HMTA), or tetramethylamonium hydroxide (TMAOH). N2 physisorption results demonstrated the materials have SBET values ranging from 1755 to 2562 m² g−1. The XPS analysis evidenced that all NACs showed relative N-surface composition from 6.40% to 17.1%. Raman spectra and SEM images proved the N-doping caused a great damage to the surface of the materials. Low-pressure CO2 adsorption results demonstrated that qe values ranged from 4.16 to 5.30 mmol g−1. Amongst NACs, the material AC2MM showed the lowest SBET value (1755 m² g−1), the highest N surface content (17.1%), and the highest CO2 qe values (5.30 mmol g−1 at 273 K and 1.0 bar, and 22.60 mmol g−1 at 298 K and 45 bar). Thus, the results evidence that N-doping tends to contribute more for CO2 adsorption than extremely high surface area values.
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