高吸水性高分子
丙烯酸
热重分析
丙烯酰胺
蒸馏水
水溶液
聚合物
壳聚糖
高分子化学
聚合
核化学
傅里叶变换红外光谱
聚电解质
材料科学
自由基聚合
化学
化学工程
共聚物
有机化学
色谱法
工程类
作者
Fang Shixin,Guangjian Wang,Ronge Xing,Xiaolin Chen,Song Liu,Qin Yukun,Li Kecheng,Wang Xueqin,Li Rongfeng,Pengcheng Li
标识
DOI:10.1016/j.ijbiomac.2019.03.176
摘要
A new kind of eco-friendly superabsorbent polymer was successfully synthesized using (2-pyridyl) acetyl chitosan chloride (PACS), acrylic acid (AA) and acrylamide (AM) in aqueous solution by a free radical polymerization. The effect of different reaction conditions, such as the initiator content, crosslinker content and PACS content were investigated. And the water retention, salt tolerance and reuse ability were investigated too. The chemical structure and morphological characterizations of the superabsorbent polymer were investigated by Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Thermogravimetric analysis (TGA) and Scanning electron microscope (SEM). The results showed that the novel superabsorbent polymer exhibits excellent water absorbency, which can absorb distilled water 615 g/g and 0.9% NaCl solution 44 g/g. At the same time, this product showed excellent water retention and reusability. The antibacterial properties of the superabsorbent polymers were tested too. The introduction of antibacterial groups also enhances antibacterial properties against Escherichia coli and Staphylococcus aureus. This kind of superabsorbent polymer has a broad application prospect.
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