Materials for Electrochemiluminescence: TADF, Hydrogen‐Bonding, and Aggregation‐ and Crystallization‐Induced Emission Luminophores

Abstract Electrochemiluminescence (ECL) is a rapidly growing discipline with many analytical applications from immunoassays to single‐molecule detection. At the forefront of ECL research is materials chemistry, which looks at engineering new materials and compounds exhibiting enhanced ECL efficiencies compared to conventional fluorescent materials. In this review, we summarize recent molecular design strategies that lead to high efficiency ECL. In particular, we feature recent advances in the use of thermally activated delayed fluorescence (TADF) emitters to produce enhanced electrochemiluminescence. We also document how hydrogen bonding, aggregation, and crystallization can each be recruited in the design of materials showing enhanced electrochemiluminescence.