催化作用
钴
分子内力
一氧化碳
电化学
化学
分子间力
二氧化碳电化学还原
堆积
选择性
光化学
无机化学
分子
有机化学
电极
物理化学
作者
Hua Jiang,Yajing Di,Yunle Gu,Yu Chen,Meiling Dou,Zhengping Zhang,Feng Wang
摘要
One type of carbonyl-linked cobalt polyphthalocyanine (CL-CoPPc) is synthesised as catalysts for use in electrochemical carbon dioxide (CO2) reduction (ECR). Carbonyl linkages can decrease the intermolecular π-π stacking, and serve as intramolecular "gullies" to impede proton transfer and the hydrogen evolution reaction (HER). Therefore, the CL-CoPPc exhibits highly active and selective CO2 reduction to carbon monoxide (CO).
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