模板
金属有机骨架
材料科学
八面体
垂直的
格子(音乐)
六方晶系
外延
纳米技术
结晶学
化学工程
晶体结构
几何学
化学
数学
物理
工程类
物理化学
吸附
声学
图层(电子)
作者
Sujeong Lee,Gihyun Lee,Moonhyun Oh
出处
期刊:ACS Nano
[American Chemical Society]
日期:2021-11-04
卷期号:15 (11): 17907-17916
被引量:16
标识
DOI:10.1021/acsnano.1c06207
摘要
Constructing metal-organic frameworks (MOFs) to have a desired structure from the given components is critical to achieve ideal MOFs with optimal properties. However, thermodynamics and/or kinetics typically impose a restriction on MOF structures. Here, we report the MOF farming concept to produce a naturally nonpreferred structure from the given components. The HKUST-1 template offers ideal places for the efficient seeding and epitaxial growth of Ga-MIL-88B that is a naturally nonpreferred structure however intentionally produced instead of the preferred Ga-MIL-68. The MOF growth on the differently shaped HKUST-1 templates (octahedral, cuboctahedral, and cubic), containing different exposed lattices, proves that a hexagonal lattice with an exposed {111} plane of HKUST-1 selectively directs the perpendicular growth of Ga-MIL-88B, owing to the lattice matching with the {001} plane of Ga-MIL-88B. The grown Ga-MIL-88B is isolated in a pure form, and the refreshed template is reused to grow additional Ga-MIL-88B.
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