水滑石
吸附
水溶液
化学
煅烧
核化学
朗缪尔吸附模型
衍射仪
没食子酸
傅里叶变换红外光谱
无机化学
有机化学
催化作用
化学工程
晶体结构
抗氧化剂
工程类
作者
Sri Juari Santosa,Philip Anggo Krisbiantoro,Elianasari,. Sutarno
标识
DOI:10.1080/03067319.2020.1807972
摘要
Gold recovery from secondary resources has been an interesting topic due to its high market prices and vast industrial applications. Reductive adsorption is a new promising technique that provides a cost-effective, efficient and eco-friendly way for gold recovery. In this study, we prepared a gallic acid-functionalised Mg/Al hydrotalcite (Mg/Al HT-GA) as well as first and second refunctionalised calcined Mg/Al hydrotalcite (Mg/Al CHT-GA_1 and Mg/Al CHT-GA_2) for reductive adsorption of AuCl4− in aqueous solution. The as-prepared adsorbents were characterised using a Fourier transform infrared (FTIR) spectrometer, an X-ray diffractometer (XRD) and a scanning electron microscope (SEM). Adsorption test showed that Mg/Al HT-GA, Mg/Al CHT-GA_1 and Mg/Al CHT-GA_2 were effective in adsorbing AuCl4 – at pH 3 with adsorption capacities (b) according to Langmuir isotherm model were 175.43, 112.36 and 86.20 mg g–1, respectively. Kinetics study showed that all adsorbents followed pseudo-second order with rate constant (kp2) of 9.81 × 10–4, 33.17 × 10–4 and 9.80 × 10–4 g/(mg.min) for Mg/Al HT-GA, Mg/Al CHT-GA_1 and Mg/Al CHT-GA_2, respectively. The characterisation of the spent adsorbent by using an XRD showed that Au(0) was formed. It was revealed that phenolic – OH groups of gallic acid played a key role for the reduction mechanism of Au(III).
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