Metal–organic framework structures of fused hexagonal motifs with cuprophilic interactions of a triangular Cu(i)3(pyrazolate-benzoate) metallo-linker

The hexagonal motifs dictated by the {Cu 3 } pyrazolate triangular units are joined together by the additional connectivity of the various alternating zinc (oxo)carboxylate units to form 2D/3D open structures (* relates the same example-structure).