磷化物
阳极
材料科学
双金属片
二聚体
电解质
电化学
硒化物
化学工程
无机化学
金属
电极
物理化学
冶金
化学
有机化学
硒
工程类
溶剂
作者
Guoping Liu,Yang Yang,Xiaoyi Lu,Fangya Qi,Yaohua Liang,А.В. Труханов,Yanxue Wu,Zhipeng Sun,Xia Lu
标识
DOI:10.1021/acsami.2c03813
摘要
Metal phosphides are promising candidates for sodium-ion battery (SIB) anode owing to their large capacities with suitable redox potential, while the reversibility and rate performances are limited due to some electrochemically inactive transition-metal components and sluggish reaction kinetics. Here, we report a fully active bimetallic phosphide Zn0.5Ge0.5P anode and its composite (Zn0.5Ge0.5P-C) with excellent performance attributed to the Zn, Ge, and P components exerting their respective Na-storage merit in a cation-disordered structure. During Na insertion, Zn0.5Ge0.5P undergoes an alloying-type reaction, along with the generation of NaP, Na3P, NaGe, and NaZn13 phases, and the uniform distribution of these phases ensures the electrochemical reversibility during desodiation. Based on this reaction mechanism, excellent electrochemical properties such as a high reversible capacity of 595 mAh g-1 and an ultrafast charge-discharge capability of 377.8 mAh g-1 at 50C for 500 stable cycles were achieved within the Zn0.5Ge0.5P-C composite in a diglyme-based electrolyte. This work reveals the Na-storage reaction mechanism within Zn0.5Ge0.5P and offers a new perspective on designing high-performance anodes.
科研通智能强力驱动
Strongly Powered by AbleSci AI