星团(航天器)
纳米材料
纳米技术
自组装
材料科学
纳米结构
多金属氧酸盐
图层(电子)
化学
催化作用
计算机科学
有机化学
程序设计语言
作者
Shengsun Hu,Xi Ling,Tian Lan,Xun Wang
标识
DOI:10.1002/chem.200902113
摘要
Abstract MoO 3 has a unique rigid double‐layer structure, which makes it a real challenge to prepare nanotubular structures. The controlled synthesis of MoO 3 single‐walled nanotubes (SWNTs) is achieved through a cluster‐based self‐assembly route on the dodecanethiol/water interface. Various factors are studied at length, including precursor type, reaction time, temperature, pH value, and their influence on the morphology of products. The concept of “self‐assembly—from simple clusters to nanostructures” is proposed here based on preliminary results from the synthesis of MoO 3 SWNTs, which provides a new aspect for traditional synthetic chemistry of nanomaterials and polyoxometalates.
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