化学
磷化氢
配体(生物化学)
催化作用
有机化学
组合化学
受体
生物化学
作者
Liguang Gan,Changxu Ye,T.-W. Pi,Lingling Wang,Chunya Li,Long Liu,Tianzeng Huang,Tieqiao Chen,Li‐Biao Han
标识
DOI:10.1021/acs.joc.4c00439
摘要
An efficient method for the construction of C–P(V) and C–P(III) bonds via the iron-catalyzed phosphorylation of alcohols under ligand-free conditions is disclosed. This strategy represents a straightforward process to prepare a series of phosphine oxides and phosphine compounds in good to excellent yields from the readily available alcohols and P–H compounds. A plausible mechanism is also proposed. We anticipate that this mode of transforming simple alcohols would apply in chemical synthesis widely.
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