纳米笼
阴极
材料科学
电化学
电解质
氧化钌
氧化物
量子点
化学工程
纳米技术
电化学动力学
储能
超级电容器
电极
化学
冶金
催化作用
物理化学
生物化学
功率(物理)
物理
量子力学
工程类
作者
Xinliang Han,Xiangyu Kong,Dewei Wang,Xu Li,Liubing Dong
标识
DOI:10.1016/j.cej.2023.147078
摘要
Zn-ion hybrid capacitors (ZICs) are a novel and promising electrochemical energy storage system, while exploring high-performance cathode materials is essential for the development of ZICs. Herein, we propose hydrous ruthenium oxide quantum dots (RuO2 QDs) anchored on porous carbon nanocages (PCNCs) as a new cathode material for ZICs. For the RuO2 QDs@PCNCs material, hydrous RuO2 QDs with a small size of 2–3 nm uniformly disperse on the PCNC support, providing large electrode–electrolyte interface for electrochemical reactions and abundant active sites for ion storage. Consequently, the RuO2 QDs@PCNCs cathode material displays desirable electrochemical performance in ZICs, including a large capacity of 224 mAh g−1 at 0.4–1.8 V, superior rate capability (showing 156 mAh g−1 capacity even at a large current of 20 A g−1) and good stability during a long-term cycling test over 20,000 cycles, significantly superior to currently-reported cathode materials for ZICs. An ultrahigh energy density of 180 Wh/kg is achieved for the RuO2 QDs@PCNCs cathode-based ZICs. Mechanism investigations point out the capacitive behavior-dominated and Zn2+/H+ co-participated charge storage process with fast electrochemical kinetics for the RuO2 QDs@PCNCs cathode in ZICs. This work not only provides a new choice for high-performance cathodes but also enriches the electrochemical theory of ZICs.
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