铈
氧化还原
选择性催化还原
吸附
催化作用
铜
化学
无机化学
核化学
X射线光电子能谱
化学工程
物理化学
有机化学
工程类
作者
Xiaoliang Li,Jiling Feng,Zhigang Xu,Junqiang Wang,Yujie Wang,Wei Zhao
标识
DOI:10.1007/s11144-019-01621-w
摘要
A series of Ce-Cu-SSZ-13 catalysts were synthesized by the ion exchange method based on the Cu-SSZ-13 prepared via a one-pot method and investigated for the selective catalytic reduction by NH3. Compared with Cu-SSZ-13, the catalytic activity and sulfur resistance of Ce-Cu-SSZ-13 were enhanced by modifying with cerium. XRD, N2-BET, MP-AES, XPS, H2-TPR and in situ DRIFTS were carried out to characterize the catalysts. XPS results suggested that more active sites on the surface of Ce-Cu-SSZ-13 catalysts. H2-TPR showed that the redox capacity of the Cu-SSZ-13 catalyst was enhanced after doping with Ce. In situ DRIFTS results demonstrated that the synergistic effect existing between copper and cerium species enhanced the adsorption performance of NH3 and NO + O2 on the catalyst surface. All of the above factors played important roles for achieving the high NH3-SCR performance.
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