二氟甲烷
化学
汽液平衡
状态方程
热力学
二进制数
二进制系统
亥姆霍兹自由能
非随机双液模型
制冷剂
物理化学
物理
色谱法
活度系数
数学
算术
气体压缩机
水溶液
作者
Pierre Six,Alain Valtz,Yue Zhou,Zhiqiang Yang,Christophe Coquelet
标识
DOI:10.1016/j.fluid.2024.114072
摘要
In this study, we present new experimental data of vapor–liquid equilibrium for the binary system difluoromethane (R32) + 1,3,3,3-tetrafluoropropene (R1234ze(E)), measured at 273.14 and 363.32 K and at pressure ranging from 0.1568 to 4.3553 MPa. A "static-analytic"-type apparatus is used to do the measurements, with sampling of the equilibrium phases via capillary sampler (ROLSI®). We used three different models to correlate the data: 1) the Peng–Robinson cubic equation of state combined with the NRTL excess free energy model and Wong-Sandler mixing rules, 2) Helmholtz energy model like the one incorporated in REFPROP 10.0 software and 3) Predictive PPR78 model for which the new group parameter of R32 was adjusted. All of the three models show a very good agreement with the experimental data except for temperature higher that R32 critical temperature.
科研通智能强力驱动
Strongly Powered by AbleSci AI