对苯二甲酸
乙烯
蒽醌
傅里叶变换红外光谱
水解
单体
材料科学
染色
聚酯纤维
对苯二甲酸二甲酯
产量(工程)
降级(电信)
有机化学
色度
聚合物
化学
化学工程
核化学
复合材料
催化作用
工程类
物理
光学
电信
计算机科学
作者
Yanyan Li,Hongling Yi,Mengjuan Li,Mingqiao Ge,Donggang Yao
标识
DOI:10.1016/j.jclepro.2022.132985
摘要
The grand challenge in chemical recycling of colored poly(ethylene terephthalate) (PET) wastes is to achieve cost-effective decolorization and purification of products. In the present work, an effective method combining hydrolysis, reactive processing and decoloration was developed to convert colored PET fabrics into high purity terephthalic acid (TPAca). Identification of intermediates and quantification of products were carried out by a range of characterizations, including SEM, EDS, TGA, FTIR, XRD, NMR and GPC. The color removal efficiency and selectivity and yield of the synthesized TPAca were calculated with the assistance of UV–vis, K/S values and chromaticity diagram to evaluate the viability of the method. It is found that disperse dyes with different structures (azo and anthraquinone) can be decolorized simultaneously with PET degradation under the joint effects of sublimation, pyrolysis and hydrolysis. In the process, calcium terephthalate (CaTP) acts as an essential medium to store and protect the synthesized TPAca. Overall, the purity of the obtained TPAca is comparable to that of commercial TPA. The monomer yield (88.51%) and decolorization rate (94.22–97.65%) are higher than TPAna produced from traditional hydrolysis. Along with future development towards sustainability, we anticipate that this method could be utilized as a basis for recycling and upcycling of complex colored PET wastes at an industrial level.
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