兴奋剂
材料科学
钴
氧化物
相(物质)
氧气
单斜晶系
自行车
化学工程
结晶学
纳米技术
晶体结构
化学
光电子学
冶金
考古
有机化学
工程类
历史
作者
Yuhang Fan,Emilia Olsson,Gemeng Liang,Zhijie Wang,Anita M. D’Angelo,Bernt Johannessen,Lars Thomsen,Bruce C. C. Cowie,Jingxi Li,Fangli Zhang,Yunlong Zhao,Wei Pang,Qiong Cai,Zaiping Guo
标识
DOI:10.1002/anie.202213806
摘要
The application of Li-rich layered oxides is hindered by their dramatic capacity and voltage decay on cycling. This work comprehensively studies the mechanistic behaviour of cobalt-free Li1.2 Ni0.2 Mn0.6 O2 and demonstrates the positive impact of two-phase Ru doping. A mechanistic transition from the monoclinic to the hexagonal behaviour is found for the structural evolution of Li1.2 Ni0.2 Mn0.6 O2, and the improvement mechanism of Ru doping is understood using the combination of in operando and post-mortem synchrotron analyses. The two-phase Ru doping improves the structural reversibility in the first cycle and restrains structural degradation during cycling by stabilizing oxygen (O2- ) redox and reducing Mn reduction, thus enabling high structural stability, an extraordinarily stable voltage (decay rate <0.45 mV per cycle), and a high capacity-retention rate during long-term cycling. The understanding of the structure-function relationship of Li1.2 Ni0.2 Mn0.6 O2 sheds light on the selective doping strategy and rational materials design for better-performance Li-rich layered oxides.
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