Dual responsive cellulose-based fluorescent material fabricated in a CO2 switchable solvent for multifunctional applications

A novel dual-responsive cellulose-based fluorescent material was fabricated in a CO 2 switchable solvent, which could be used as smart probe for “turn off” for Fe 3+ detection, “turn on” for freshness monitor, and “turn-on-turn-off” for information encryption . • Cellulose was employed for the fabrication of dual-responsive fluorescent materials. • The CO 2 switchable solvent system was used for the highly effective dissolution and functionalization of cellulose . • The turn-off fluorescent responsive ability towards Fe 3+ is due to the coordination of Fe 3+ with the carbonate linkage. • The turn-on fluorescent responsive ability towards amine is due to the remove of the acetyl group by aminolysis reaction. • The combination of the dual-responsive property enables the application in the field of information encryption. Fabrication of multi-responsive fluorescent sensors for real-time and visual monitoring or detection is practical and challenging. Herein, a novel cellulose-based fluorescent functional material with dual-responsive properties arising from two different functional sites was successfully designed and prepared in a CO 2 switchable solvent. Cellulose was effectively dissolved in this solvent and easily functionalized by successively grafting poly (lactic acid) and 7-hydroxy-4-trifluoromethyl coumarin (HFC) onto the cellulose backbone, resulting in C- g -PLLA/HFC with good processibility and fluorescence quenching response (turn off) towards Fe 3+ due to the coordination of Fe 3+ with the carbonate linkage. Acetylation of HFC under microwave-assisted conditions gave rise to C- g -PLLA/HFC-Ac which showed fluorescence enhancement response (turn on) to various organic amines because of the removal of the acetyl group by aminolysis reaction. Therefore, they could be respectively used for selective identification and detection of Fe 3+ , and real-time, accurate and visual monitoring of aquatic product freshness. Furthermore, an interesting application for irreversible information encryption was demonstrated by combining the dual-responsive property. This study suggests a new strategy for constructing cellulose-based functional material with multiple responsiveness and applications.