X射线光电子能谱
半导体
三元运算
材料科学
光催化
光化学
催化作用
化学工程
纳米技术
光电子学
化学
计算机科学
生物化学
工程类
程序设计语言
作者
Rongchen Shen,Xinyong Lu,Qiaoqing Zheng,Qing Chen,Yun Hau Ng,Peng Zhang,Xin Li
出处
期刊:Solar RRL
[Wiley]
日期:2021-05-16
卷期号:5 (7)
被引量:116
标识
DOI:10.1002/solr.202100177
摘要
Developing efficient and low‐cost photocatalysts and deep investigations on the charge separation and transfer pathways are still two key challenges in achieving practical photocatalytic application. Herein, the NiS‐modified Mo 2 C/CdS layered nanojunction with cascade 2D coupling interfaces for efficient photocatalytic H 2 evolution is constructed. The as‐prepared ternary step‐scheme (S‐scheme) photocatalysts show excellent photocatalytic hydrogen‐evolution performance of 24.03 mmol g −1 h −1 , which is 7.83 and 3.83 times higher than that of CdS and CdS/NiS. Surprisingly, it is found that Mo 2 C can serve as a semiconductor in photocatalytic hydrogen evolution, instead of as a cocatalyst. The charge transfer pathways from Mo 2 C to CdS are identified via both, in situ irradiation X‐ray photoelectron spectroscopy (XPS) (ISI XPS) and ultraviolet photoelectron spectroscopy (UPS). Notably, this is the first report using Mo 2 C as a semiconductor for photocatalytic application, which gives full play to the advantages of light‐harvesting and charges separation.
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