氢胺化
化学
分子间力
催化作用
炔烃
药物化学
有机化学
组合化学
分子
作者
Tomohiro Shimada,Gan B. Bajracharya,Yoshinori Yamamoto
标识
DOI:10.1002/ejoc.200400568
摘要
Abstract The intermolecular hydroamination of alkynes proceeds very smoothly in the presence of a catalytic amount of the aquapalladium complex [Pd(dppe)(H 2 O) 2 ](TfO) 2 . This reaction most probably proceeds through the formation of an equilibrium between the hydroxopalladium and the amidopalladium complexes, and subsequent aminopalladation of alkynes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
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