Scalable Li‐Ion Battery with Metal/Metal Oxide Sulfur Cathode and Lithiated Silicon Oxide/Carbon Anode

Abstract A Li‐ion battery combines a cathode benefitting from Sn and MnO 2 with high sulfur content, and a lithiated anode including fumed silica, few layer graphene (FLG) and amorphous carbon. This battery is considered a scalable version of the system based on lithium‐sulfur (Li−S) conversion, since it exploits at the anode the Li‐ion electrochemistry instead of Li‐metal stripping/deposition. Sn and MnO 2 are used as cathode additives to improve the electrochemical process, increase sulfur utilization, while mitigating the polysulfides loss typical of Li−S devices. The cathode demonstrates in half‐cell a maximum capacity of ~1170 mAh g S −1 , rate performance extended over 1 C, and retention of 250 cycles. The anode undergoes Li‐(de)alloying with silicon, Li‐(de)insertion into amorphous carbon, and Li‐(de)intercalation through FLG, with capacity of 500 mAh g −1 in half‐cell, completely retained over 400 cycles. The full‐cells are assembled by combining a sulfur cathode with active material loading up to 3 mg cm −2 and lithiated version of the anode, achieved either using an electrochemical pathway or a chemical one. The cells deliver at C/5 initial capacity higher than 1000 mAh g S −1 , retained for over ~40 % upon 400 cycles. The battery is considered a promising energy storage system for possible scaling‐up in pouch or cylindrical cells.