Research on the electrochemical treatment of nitrobenzene wastewater: The effects of process parameters and the mechanism of distinct degradation pathways

Nitrobenzene is a typical organic pollutant of petroleum pollutant, which is a synthetic chemical not found naturally in the environment. Nitrobenzene in environment can cause toxic liver disease and respiratory failure in humans. Electrochemical technology provides an effective and efficient method for degrading nitrobenzene. This study, the effects of process parameter (e.g., electrolyte solution type, electrolyte concentration, current density and pH) and distinct reaction pathways for electrochemical treatment of nitrobenzene were investigated. As a result, available chlorine dominates the electrochemical oxidation process compared with hydroxyl radical, thus the electrolyte of NaCl is more suitable for the degradation of nitrobenzene than that of Na2SO4. The concentration and the existence form of available chlorine were mainly controlled by electrolyte concentration, current density and pH, which directly affect the removal of nitrobenzene. Cyclic voltammetry and mass spectrometric analyses suggested that electrochemical degradation of nitrobenzene included two important ways. Firstly, single oxidation: nitrobenzene → other forms of aromatic compounds→ NO-x + organic acids + mineralization products. Secondly, coordination of reduction and oxidation: nitrobenzene → aniline→ N2 + NO-x + organic acid + mineralization products. The results of this study will encourage us to further understand the electrochemical degradation mechanism of nitrobenzene and develop the efficient processes for nitrobenzene treatment.