A Porphyrin-Phenylalkynyl-Based Conjugated Organic Polymer as a High-Performance Cathode for Rechargeable Organic Batteries

Organic electrode materials (OEMs) have attracted much attention for rechargeable batteries due to their low cost, environment friendliness, flexibility, and structural versatility. Despite the above advantages, high solubility in electrolyte and low electronic conductivity remain critical limitations for the application of OEMs. In this work, the conjugated organic polymer (COP) poly([5,10,15,20-tetrakis(4-phenylalkynyl)porphyrin]Cu(II)) (PCuTPEP) is proposed as a cathode for high performance in organic lithium batteries. The polymerization inhibits the dissolution of the organic electrodes in the electrolyte, and the porphyrin and ethynyl-phenyl groups greatly expand the conjugated system and result in a high average discharge plateau at 4.0 V (vs Li