Geomechanical Properties of Clay Stabilised with Fly Ash-Based Geopolymer Subjected to Long-Term Sulfate Attack

Abstract Fly ash-based geopolymers have emerged as an eco-friendly alternative binder compared to conventional Portland cement for soil stabilisation. However, the gap in the current literature is the lack of a comprehensive study regarding the geomechanical behaviour of fly ash geopolymer-treated clay subjected to long-term sulfate attack, particularly in terms of potential ettringite formation and the corresponding impact on cementitious soil structure. The goal of this paper is to address this knowledge gap and provide a comprehensive study to fulfil it. In this work, sulfate attack was simulated by submerging geopolymer-treated clay specimens in two distinct sulfate-based solutions (i.e., sodium and magnesium), for one year. Subsequently, comparative analyses of the geomechanical and microstructural changes in geopolymer-treated clay under various curing conditions were conducted through unconfined compressive strength, direct shear, volume change and microscopic tests. The findings indicate that the addition of geopolymer for the stabilisation of clay soil significantly improves soil strength without affecting the soil volumetric response. Although the clay used exhibited similar qualitative stress–strain behaviour across all simulated attacks, notable quantitative differences emerged in the peak strength, stiffness and shear strength parameters. Such discrepancies can primarily be attributed to the varying buffering capacities (i.e., pH changes associated with acidification) of the sulfate solutions and the subsequent residual pH, cementitious product formation and strength enhancement within the treated clay.