Combining non-thermal plasma technology with photocatalysis: a critical review

Due to the excellent application prospects in the fields of new energy generation and environmental remediation, photocatalysis technology has attracted the increasing attention of researchers. Although significant progress has been made in the past decades, the practical application of this technology is still restricted by the moderate catalytic efficiency. To improve the performance of catalysts, new methods are extremely required for the controllable synthesis of high-efficiency catalysts. To further comprehend the relationship between material structure and catalytic activity, the surface active sites of catalysts should be regulated at the atomic and molecular levels. As the fourth state of matter, plasma can generate diverse active species with low energy consumption. As a subset of plasmas, non-thermal plasma (NTP), defined by the great temperature difference between ions (near room temperature) and electrons (usually hotter than 2 orders of magnitude), contributes to the rapid synthesis of functional nanomaterials under relatively mild conditions. Furthermore, NTP has been widely used for the surface modification of materials. Therefore, the combination of NTP and photocatalysis is expected to provide an ideal approach to synthesize high-performance catalysts and precisely customize their surface structures, which is becoming a new direction in the field of catalysis research. This paper fundamentally reviews the progress in the combination of NTP with photocatalysis for versatile applications. Beginning with the principles of photocatalysis and plasma technology, the application of NTP for catalyst synthesis, the plasma-assisted modification of surface actives sites, and the impact of plasma-involved processes on the catalytic performance are discussed, which will provide useful insights into the performance enhancement of catalysts via plasma-assisted processes.