阳离子聚合
锆
纳米尺度
金属
金属有机骨架
材料科学
高分子化学
无机化学
纳米技术
化学
有机化学
冶金
吸附
作者
Dechen Zhang,Lihong Chen,Yintao Li,Qingqing Zuo,Gōngyín Yè,Pengfei Ji
出处
期刊:ACS applied nano materials
[American Chemical Society]
日期:2024-02-06
标识
DOI:10.1021/acsanm.3c05842
摘要
A nanoscale metal–organic framework (MOF) based on zirconium, featuring the stacking of a layered structure, has been successfully synthesized. The linear dicarboxylic acid ligand FeTPY2 was built from a unique coordination–dimerization strategy, through the coordination of terpyridyl group with ferrous ions. This approach offers a methodology for extending the length of ligands, which is rarely employed in the MOF design. Subsequently, this ligand was used for making Zr-FeTPY2. The deliberate incorporation of cationic Fe2+ units within Zr-FeTPY2 renders it highly effective in the selective adsorption of anionic dyes, with a loading capacity of 2.84 g/g for Acid Red 94. This result demonstrates the superiority of the developed Zr-FeTPY2 over charge-neutral UiO-68, providing a viable strategy for sustainable water treatment and dye recovery.
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