电致变色
共轭体系
低聚物
噻吩
化学
三噻吩
部分
烷基
光化学
吲哚试验
高分子化学
堆积
光致发光
组合化学
有机化学
聚合物
材料科学
电极
物理化学
光电子学
作者
Ben Dong,Baoyan Li,Yi Cao,Xinlei Meng,Han Yan,Shusheng Ge,Yun Lu
标识
DOI:10.1016/j.tetlet.2016.11.090
摘要
Two series of thiophene oligomers and terthiophene oligomers consisting of both thiophene and indole moieties have been synthesized. They have same excitation-dependent photoluminescence characteristics, but different bandgaps and absorption behaviors, which relates to the number and denseness of indoles in the conjugated oligomers and the length of alkyl chains on indole moiety due to varied the π-π stacking interaction of conjugated structures in the as-prepared oligomers. A simple electrochromic device based on such a conjugated oligomer displays a novel four-color electrochromism from red to yellow, green and puce with the increased potential and possesses good environmental and redox stability. Such conjugated oligomer also exhibits high sensitivity and selectivity for Zn2+ detection.
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