材料科学
黄铜矿
阳极
复合数
集电器
升华(心理学)
极化(电化学)
复合材料
化学工程
金属
涂层
电流密度
碳纤维
电镀(地质)
电极
电解质
冶金
铜
化学
物理化学
心理治疗师
地球物理学
工程类
地质学
物理
量子力学
心理学
作者
Xinyang Yue,Xun‐Lu Li,Weiwen Wang,Dong Chen,Qi‐Qi Qiu,Qin‐Chao Wang,Xiaojing Wu,Zheng‐Wen Fu,Zulipiya Shadike,Xiao‐Qing Yang,Yong‐Ning Zhou
出处
期刊:Nano Energy
[Elsevier]
日期:2019-06-01
卷期号:60: 257-266
被引量:116
标识
DOI:10.1016/j.nanoen.2019.03.057
摘要
Li metal anode has received extensive attention due to its high specific capacity and low potential vs. Li/Li+ for lithium batteries. However, dendrite growth, volume change and "dead" Li formation during cycling hinder its practical application. Here we report an innovated cuprite-coated carbon felt as current collector, with ultralight 3D framework and significantly improved Li-metal loading through thermal infusion. The Li-metal anode has a high Li content of 90 wt.%. The cuprite coating improves the lithiophilicity of carbon felt remarkably, due to the surface affinity reaction between cuprite and Li. The porous carbon felt provides good electronic connection and buffer space to accommodate volume change during Li stripping/plating. It leads to uniformly distributed local current density and preference of Li stripping/plating in the highly dispersed concave areas, with suppressed formation of dendrites and “dead” Li. The Li composite electrode shows excellent cycle stability with low polarization in both symmetric and full cells. This work opens a new approach for the development of high loading Li composite anodes for advanced Li metal batteries.
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